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Best Synthetic Methods: Carbon-Carbon Bond Construction

Chemexpress May 25, 2024 0 Comments

In the context of peptidyl ketone synthesis, Troels Skrydstrup of the University of Aarhus developed (J. Org. PMID:24377291 Chem. 2008, 73, 1088. DOI: 10.1021/jo702286b) the elegant SmI2-mediated conjugate addition of…

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Developments in Alkene Metathesis

Chemexpress May 25, 2024 0 Comments

Hervé Clavier and Steven P. Nolan, now at St. Andrew’s University, found (Adv. Synth. Catal. 2008, 350, 2959.DOI: 10.1002/adsc.200800495)that the indenylidene Ru complex 1 was an excellent pre-catalyst for alkene…

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Practical Enantioselective Construction of Arrays of Stereogenic Centers:

Chemexpress May 25, 2024 0 Comments

The Jørgensen Synthesis of the Autoregulator IM-2 Amando Córdova of Stockholm University found (Angew. Chem. Int. Ed. 2008, 47, 8468. DOI: 10.1002/anie.200802335) that the enantiomerically-enriched diastereomers from aminosulfenylation of 1…

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Organocatalytic C-C Ring Construction: (+)-Ricciocarpin A (List) and (-)-Aromadendranediol

Chemexpress May 25, 2024 0 Comments

(MacMillan) Yoshiji Takemoto of Kyoto University designed (Org. 288617-73-2 Chemscene Lett. 2009, 11, 2425. DOI: 10.1021/ol9006053) an organocatalyst for the enantioselective conjugate addition of alkene boronic acids to γ-hydroxy enones,…

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Preparation of Heteroaromatics

Chemexpress May 25, 2024 0 Comments

Masahiro Yoshida of the University of Tokushima described(Tetrahedron Lett. 2008, 49, 5021.DOI: 10.1016/j.tetlet.2008.06.043)the Pt-mediated rearrangement of alkynyl oxiranes such as 1to the furan 2. Roman Dembinski of Oakland University reported(J.…

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Stereoselective C-O Ring Construction: The Oguri-Oikawa Synthesis of Lasalocid A

Chemexpress May 25, 2024 0 Comments

O-Centered radicals have been little used for C-O ring formation. PMID:24633055 Glenn M. Sammis of the University of British Columbia showed (Org. Lett. 2008, 10, 5083 DOI: 10.1021/ol802142k) that O-centered…

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So et al., 2006). Taking into consideration the micromolar concentrations of nitrate out there in

Chemexpress May 24, 2024 0 Comments

So et al., 2006). Thinking of the micromolar concentrations of nitrate out there inside the aquifer (Williams et al., 2011), this might also reasonably clarify the enrichment of bacteria in…

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Icentric, randomized, controlled trial to assess blood glucose control through the

Chemexpress May 24, 2024 0 Comments

Icentric, randomized, controlled trial to evaluate blood glucose management through the model predictive management algorithm versus regimen glucose management protocols in intensive care unit sufferers. Diabetes Care 2006, 29(2):271-276. 44.…

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Substituted Benzenes: The Alvarez-Manzaneda Synthesis of (-)-Taiwaniquinone

Chemexpress May 24, 2024 0 Comments

G Continuing efforts toward the direct functionalization of aromatic C-H bonds, Nobutaka Fujii and Hiroaki Ohno of Kyoto University described (Chem. Commun. 2009, 3413. DOI: 10.1039/b905586j) a Pd-mediated protocol for…

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Advances in Alkene and Alkyne Metathesis

Chemexpress May 24, 2024 0 Comments

As alkene metathesis is extended to more and more challenging substrates, improved catalysts and solvents are required. Robert H. 233276-38-5 manufacturer Grubbs of Caltech developed (Org. Lett. tBuBrettPhos Pd G3…

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T106C Rabbit Polyclonal Antibody

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Tions differ in their composition, which complicates comparison of research [85]. Dried

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Smad3 Rabbit Polyclonal Antibody

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Eria revealed that the 3 major families Methylococcaceae, Methylocystaceae, and Beijerinckiaceae

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